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The best moveset for Iron Moth in the current competitive meta typically features the moves its most common attacks.
In the Pokémon Champions meta, Iron Moth can be countered by exploiting its weaknesses (ground 4x, psychic 2x, rock 2x, water 2x) and using effective check/counter teams.
The best item for Iron Moth is typically Leftovers, based on high-level tournament and ladder stats.